Skip to main content
Global

5.8: Dipolos elétricos

  1. Last updated
  2. Save as PDF
  • Page ID
    184569

    • \( \newcommand{\vecs}[1]{\overset { \scriptstyle \rightharpoonup} {\mathbf{#1}} } \) \( \newcommand{\vecd}[1]{\overset{-\!-\!\rightharpoonup}{\vphantom{a}\smash {#1}}} \)\(\newcommand{\id}{\mathrm{id}}\) \( \newcommand{\Span}{\mathrm{span}}\) \( \newcommand{\kernel}{\mathrm{null}\,}\) \( \newcommand{\range}{\mathrm{range}\,}\) \( \newcommand{\RealPart}{\mathrm{Re}}\) \( \newcommand{\ImaginaryPart}{\mathrm{Im}}\) \( \newcommand{\Argument}{\mathrm{Arg}}\) \( \newcommand{\norm}[1]{\| #1 \|}\) \( \newcommand{\inner}[2]{\langle #1, #2 \rangle}\) \( \newcommand{\Span}{\mathrm{span}}\) \(\newcommand{\id}{\mathrm{id}}\) \( \newcommand{\Span}{\mathrm{span}}\) \( \newcommand{\kernel}{\mathrm{null}\,}\) \( \newcommand{\range}{\mathrm{range}\,}\) \( \newcommand{\RealPart}{\mathrm{Re}}\) \( \newcommand{\ImaginaryPart}{\mathrm{Im}}\) \( \newcommand{\Argument}{\mathrm{Arg}}\) \( \newcommand{\norm}[1]{\| #1 \|}\) \( \newcommand{\inner}[2]{\langle #1, #2 \rangle}\) \( \newcommand{\Span}{\mathrm{span}}\)\(\newcommand{\AA}{\unicode[.8,0]{x212B}}\)

    Objetivos de

    Ao final desta seção, você poderá:

    • Descreva um dipolo permanente
    • Descreva um dipolo induzido
    • Defina e calcule um momento de dipolo elétrico
    • Explique o significado físico do momento de dipolo

    Anteriormente, discutimos e calculamos o campo elétrico de um dipolo: duas cargas iguais e opostas que estão “próximas” uma da outra. (Nesse contexto, “próximo” significa que a distância d entre as duas cargas é muito, muito menor do que a distância do ponto de campo P, o local onde você está calculando o campo.) Vamos agora considerar o que acontece com um dipolo quando ele é colocado em um campo externo\(\vec{E}\). Assumimos que o dipolo é um dipolo permanente; ele existe sem o campo e não se separa no campo externo.

    Rotação de um dipolo devido a um campo elétrico

    Por enquanto, lidamos apenas com o caso mais simples: o campo externo é uniforme no espaço. Suponha que tenhamos a situação descrita na Figura\(\PageIndex{1}\), onde denotamos a distância entre as cargas como vetor\(\vec{d}\), apontando da carga negativa para a carga positiva.

    Na figura, um dipolo em um campo elétrico uniforme é mostrado junto com as forças nas cargas que compõem o dipolo. O dipolo consiste em uma carga, menos q, e uma carga positiva, mais q, separada por uma distância d. A linha que conecta as cargas está em um ângulo com a horizontal, de modo que a carga negativa fique acima e à esquerda da carga positiva. O campo elétrico E é horizontal e aponta para a direita. A força na carga negativa está à esquerda e é rotulada como F menos. A força na carga positiva está à direita e é rotulada como F plus. A Figura b mostra o mesmo diagrama com a adição do vetor de momento dipolar, p, que aponta ao longo da linha que conecta as cargas, da carga negativa à positiva.
    Figura\(\PageIndex{1}\): A dipole in an external electric field. (a) The net force on the dipole is zero, but the net torque is not. As a result, the dipole rotates, becoming aligned with the external field. (b) The dipole moment is a convenient way to characterize this effect. The \(\vec{d}\) points in the same direction as \(\vec{p}\).

    The forces on the two charges are equal and opposite, so there is no net force on the dipole. However, there is a torque:

    \[\begin{align} \vec{r} &= \left(\dfrac{\vec{d}}{2} \times \vec{F}_+ \right) + \left(- \dfrac{\vec{d}}{2} \times \vec{F}_- \right) \\[4pt] &= \left[ \left(\dfrac{\vec{d}}{2}\right) \times \left(+q\vec{E}\right) + \left(-\dfrac{\vec{d}}{2}\right) \times \left(-q\vec{E}\right)\right] \\[4pt] &= q\vec{d} \times \vec{E}. \end{align}\]

    The quantity \(qd\) (the magnitude of each charge multiplied by the vector distance between them) is a property of the dipole; its value, as you can see, determines the torque that the dipole experiences in the external field. It is useful, therefore, to define this product as the so-called dipole moment of the dipole:

    \[\vec{p} \equiv q\vec{d}.\]

    We can therefore write

    \[\vec{r} = \vec{p} \times \vec{E}.\]

    Recall that a torque changes the angular velocity of an object, the dipole, in this case. In this situation, the effect is to rotate the dipole (that is, align the direction of \(\vec{p}\)) so that it is parallel to the direction of the external field.

    Induced Dipoles

    Neutral atoms are, by definition, electrically neutral; they have equal amounts of positive and negative charge. Furthermore, since they are spherically symmetrical, they do not have a “built-in” dipole moment the way most asymmetrical molecules do. They obtain one, however, when placed in an external electric field, because the external field causes oppositely directed forces on the positive nucleus of the atom versus the negative electrons that surround the nucleus. The result is a new charge distribution of the atom, and therefore, an induced dipole moment (Figure \(\PageIndex{2}\)).

    Figure a illustrates a simplified model of a neutral atom. The nucleus is at the center of a uniform sphere negative charge. Figure b shows the atom in a horizontal, uniform electric field, E, that points to the right. The nucleus has shifted to the right a distance d, so that it is no longer at the center of the electron sphere. The result is an induced dipole moment, p, pointing to the right.
    Figure \(\PageIndex{2}\): A dipole is induced in a neutral atom by an external electric field. The induced dipole moment is aligned with the external field.

    An important fact here is that, just as for a rotated polar molecule, the result is that the dipole moment ends up aligned parallel to the external electric field. Generally, the magnitude of an induced dipole is much smaller than that of an inherent dipole. For both kinds of dipoles, notice that once the alignment of the dipole (rotated or induced) is complete, the net effect is to decrease the total electric field

    \[\vec{E}_{total} = \vec{E}_{external} + \vec{E}_{dipole}\]

    in the regions outside the dipole charges (Figure \(\PageIndex{3}\)). By “outside” we mean further from the charges than they are from each other. This effect is crucial for capacitors, as you will see in Capacitance.

    A dipole, consisting of a negative charge on the left and a positive charge on the right is in a uniform electric field pointing to the right. The dipole moment, p, points to the right. The field lines of the net electric field are the sum of the dipole field and the uniform external field, horizontal far from the dipole and similar to the dipole field near the dipole.
    Figure \(\PageIndex{3}\): The net electric field is the vector sum of the field of the dipole plus the external field.

    Recall that we found the electric field of a dipole. If we rewrite it in terms of the dipole moment we get:

    \[\vec{E}(z) = \dfrac{1}{4 \pi \epsilon_0} \dfrac{\vec{p}}{z^3}.\]

    The form of this field is shown in Figure \(\PageIndex{3}\). Notice that along the plane perpendicular to the axis of the dipole and midway between the charges, the direction of the electric field is opposite that of the dipole and gets weaker the further from the axis one goes. Similarly, on the axis of the dipole (but outside it), the field points in the same direction as the dipole, again getting weaker the further one gets from the charges.