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3.2: Mfumo wa Thermodynamic

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    Malengo ya kujifunza

    Mwishoni mwa sehemu hii, utaweza:

    • Kufafanua mfumo thermodynamic, mipaka yake, na mazingira yake
    • Eleza majukumu ya vipengele vyote vinavyohusika katika thermodynamics
    • Eleza usawa wa joto na joto la thermodynamic
    • Unganisha equation ya hali kwa mfumo

    Mfumo wa thermodynamic unajumuisha kitu chochote ambacho mali ya thermodynamic ni ya riba. Imeingizwa katika mazingira yake au mazingira; inaweza kubadilishana joto na, na kufanya kazi, mazingira yake kupitia mipaka, ambayo ni ukuta wa kufikiri unaotenganisha mfumo na mazingira (Kielelezo\(\PageIndex{1}\)). Kwa kweli, mazingira ya haraka ya mfumo yanaingiliana nayo moja kwa moja na kwa hiyo yana ushawishi mkubwa juu ya tabia na mali zake. Kwa mfano, ikiwa tunasoma inji ya gari, petroli inayowaka ndani ya silinda ya inji ni mfumo wa thermodynamic; pistoni, mfumo wa kutolea nje, radiator, na hewa nje huunda mazingira ya mfumo. Mpaka huo una nyuso za ndani za silinda na pistoni.

    Kielelezo unaeleza dhana ya mfumo. Mpaka hutenganisha mfumo, ndani ya mipaka, kutoka kwa mazingira, nje ya mipaka. Kielelezo b ni mfano wa kimapenzi wa silinda ya inji kama mfano wa mfumo maalum. Mfumo ni gesi ndani ya pistoni. Mpaka una mwili wa silinda ulio na gesi na pistoni inayofunika silinda hapo juu. Mazingira yanajumuisha kila kitu nje ya silinda na juu ya pistoni.
    Kielelezo\(\PageIndex{1}\): (a) A system, which can include any relevant process or value, is self-contained in an area. The surroundings may also have relevant information; however, the surroundings are important to study only if the situation is an open system. (b) The burning gasoline in the cylinder of a car engine is an example of a thermodynamic system.

    Normally, a system must have some interactions with its surroundings. A system is called an isolated and closed system if it is completely separated from its environment—for example, a gas that is surrounded by immovable and thermally insulating walls. In reality, a closed system does not exist unless the entire universe is treated as the system, or it is used as a model for an actual system that has minimal interactions with its environment. Most systems are known as an open system, which can exchange energy and/or matter with its surroundings (Figure \(\PageIndex{2}\)).

    Figure a is a photograph of a tea kettle on a stove. Steam is seen coming out of the nozzle of the kettle. Figure b is a photograph of a pressure cooker on a stove.
    Figure \(\PageIndex{2}\): (a) This boiling tea kettle is an open thermodynamic system. It transfers heat and matter (steam) to its surroundings. (b) A pressure cooker is a good approximation to a closed system. A little steam escapes through the top valve to prevent explosion. (credit a: modification of work by Gina Hamilton)

    When we examine a thermodynamic system, we ignore the difference in behavior from place to place inside the system for a given moment. In other words, we concentrate on the macroscopic properties of the system, which are the averages of the microscopic properties of all the molecules or entities in the system. Any thermodynamic system is therefore treated as a continuum that has the same behavior everywhere inside. We assume the system is in equilibrium. You could have, for example, a temperature gradient across the system. However, when we discuss a thermodynamic system in this chapter, we study those that have uniform properties throughout the system.

    Before we can carry out any study on a thermodynamic system, we need a fundamental characterization of the system. When we studied a mechanical system, we focused on the forces and torques on the system, and their balances dictated the mechanical equilibrium of the system. In a similar way, we should examine the heat transfer between a thermodynamic system and its environment or between the different parts of the system, and its balance should dictate the thermal equilibrium of the system. Intuitively, such a balance is reached if the temperature becomes the same for different objects or parts of the system in thermal contact, and the net heat transfer over time becomes zero.

    Thus, when we say two objects (a thermodynamic system and its environment, for example) are in thermal equilibrium, we mean that they are at the same temperature. Let us consider three objects at temperatures \(T_1, \, T_2\), and \(T_3\) respectively. How do we know whether they are in thermal equilibrium? The governing principle here is the zeroth law of thermodynamics:

    Zeroth Law of Thermodyamics

    If object 1 is in thermal equilibrium with objects 2 and 3, respectively, then objects 2 and 3 must also be in thermal equilibrium.

    Mathematically, we can simply write the zeroth law of thermodynamics as

    \[If \, T_1 = T_2 \, and \, T_1 = T_3, \, then \, T_2 = T_3.\]

    This is the most fundamental way of defining temperature: Two objects must be at the same temperature thermodynamically if the net heat transfer between them is zero when they are put in thermal contact and have reached a thermal equilibrium.

    The zeroth law of thermodynamics is equally applicable to the different parts of a closed system and requires that the temperature everywhere inside the system be the same if the system has reached a thermal equilibrium. To simplify our discussion, we assume the system is uniform with only one type of material—for example, water in a tank. The measurable properties of the system at least include its volume, pressure, and temperature. The range of specific relevant variables depends upon the system. For example, for a stretched rubber band, the relevant variables would be length, tension, and temperature. The relationship between these three basic properties of the system is called the equation of state of the system and is written symbolically for a closed system as

    \[f(p, V, T) = 0,\]

    where \(V\), \(p\), and \(T\) are the volume, pressure, and temperature of the system at a given condition.

    In principle, this equation of state exists for any thermodynamic system but is not always readily available. The forms of \(f(p, V, T) = 0\) for many materials have been determined either experimentally or theoretically. In the preceding chapter, we saw an example of an equation of state for an ideal gas,

    \[f(p, V, T) = pV - nRT = 0. \nonumber\]

    We have so far introduced several physical properties that are relevant to the thermodynamics of a thermodynamic system, such as its volume, pressure, and temperature. We can separate these quantities into two generic categories. The quantity associated with an amount of matter is an extensive variable, such as the volume and the number of moles. The other properties of a system are intensive variables, such as the pressure and temperature. An extensive variable doubles its value if the amount of matter in the system doubles, provided all the intensive variables remain the same. For example, the volume or total energy of the system doubles if we double the amount of matter in the system while holding the temperature and pressure of the system unchanged.